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Adsorption Performance of Activated Cokes for Dry Cleaning Processes of Fuel Gas Produced in Biomass Gasification

机译:活性炭对生物质气化过程中产生的天然气干洗过程的吸附性能

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Biomass gasification is one of attractive applications into a small scale of local power generation an oil synthesis by gas-to-liquid (GTL) as a carbon neutral fuel. Then gas cleaning processes are necessary to remove contaminant from raw fuel gas.In this study, adsorption performance of activated cokes was evaluated to simultaneously remove H_2S, COS and NH3 as representative contaminants in the raw fuel gas. The activated cokes produced from coal, which is used industrially for de-SOx and de-NOx, was examined by thermo-gravimetric analyses to reveal the satisfactory adsorption and desorption behavior of H_2S, COS and NH3. The H_2S breakthrough experiment was also conducted in the fixed bed adsorption reactor, and it was confirmed that the activated cokes have an excellent performance to achieve the H2_S removal less than 1 ppm, i.e. a level applicable to fuel cells.
机译:生物质气化是一种小规模的本地发电的有吸引力的应用之一,它是一种通过气-液(GTL)作为碳中性燃料进行的石油合成。然后,必须进行气体清洁工艺以从原始燃料气体中去除污染物。 在这项研究中,对活性焦的吸附性能进行了评估,以同时去除作为原料燃料气体中代表性污染物的H_2S,COS和NH3。通过热重分析对工业上用于脱硫和脱氮的煤制得的活性焦进行了研究,以揭示H_2S,COS和NH3的令人满意的吸附和解吸性能。还在固定床吸附反应器中进行了H_2S突破实验,并且证实了活化的焦炭具有优异的性能,以实现H 2_S的去除小于1ppm,即适用于燃料电池的水平。

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