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Characterization of the van Cittert monochromator based IR spectrophotometer

机译:基于van Cittert单色仪的红外分光光度计的表征

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The van Cittert system consists of two identical monochromators coupled together as a subtractive system. The usual narrow slit between the two monochromators is replaced by a wide one and a part of this wide slit is covered by a lamella mounted on a fine resolution translating stage. The wide slit transmits a wide spectral range but the lamella filters out a narrow range like a notch filter. The second monochromater collects and recombines the transmitted radiation at its exit slit. Behind the exit slit and the beam forming elements can the sample be positioned. By the translation fo the lamella the center wavelength of the notch can be shifted over the whole spectral range covered by the wide slit. Carrying out spectrophotometric measurements the total transmitted power is measured at every stop of the lamella. From this array of measurement results the transmittance or the reflectance of the sample can be calculated as a function of the wavelength.
机译:van Cittert系统由两个相同的单色仪组成,它们作为减法系统耦合在一起。两个单色仪之间通常较窄的狭缝被宽的狭缝所代替,并且该狭缝的一部分被安装在高分辨率平移台上的薄片覆盖。宽的狭缝透射较宽的光谱范围,但薄片像陷波滤光片一样滤出较窄的范围。第二个单色仪在其出口狭缝处收集并重组透射的辐射。出口狭缝和波束形成元件的后面可以放置样品。通过薄片的平移,凹口的中心波长可以在宽狭缝覆盖的整个光谱范围内移动。进行分光光度法测量时,在每个薄片停止时都要测量总发射功率。根据该测量结果阵列,可以根据波长计算样品的透射率或反射率。

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