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THE PHOTOCHEMICAL TRANSFORMATION AT THE SURFACE OF NATURAL AND SYNTHETIC SILICATES INDUCED BY INFRARED LASER RADIATION

机译:红外激光辐射诱导的天然和合成硅酸盐表面的光化学转化

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The photochemical transformations caused by infrared CO_2 laser radiation at the surface of natural and synthetic silicates have been investigated. It has been established that by laser action on these silicates a photochemical stable line burning with the width of 50 cm~(-1) in infrared reflection spectra just at the frequency of laser action is appeared. It has been establish also, that by laser action on these matters the selective sublimation of silicon oxides and the enrichment of surface by the rest elements take place.It has been found, that all observed phenomena connect with the selective breaking of the strong covalent Si-O bonds induced by resonant laser action.
机译:研究了天然和合成硅酸盐表面的红外CO_2激光辐射引起的光化学转变。已经确定,通过对这些硅酸盐进行激光作用,在激光反射的频率上出现了在红外反射光谱中燃烧宽度为50 cm〜(-1)的光化学稳定线。还已经确定,通过对这些物质进行激光作用,发生了氧化硅的选择性升华和其余元素对表面的富集。 已经发现,所有观察到的现象都与共振激光作用引起的强共价Si-O键的选择性断裂有关。

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