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Innovative method to determine the wax content and the wax precipitation temperature simultaneously for crude oils at pipeline pressures

机译:同时测定原油在管道压力下的蜡含量和蜡沉淀温度的创新方法

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Wax content in oil and wax appearance temperature are important factors for simulation of the wax deposition profiles inpipelines. Standard acetone method (UOP method 46-64) or other slightly modified methods of this standard are traditionally used to determine the wax content in the oil. However, in order to determine the wax content at different temperatures, several runs have to be made. This is considered to be time consuming. This paper presents a new method/ approach to determine the wax content of oil at different temepratuers as well as the wax precipitation temperature from a single run. In this approach a correlation between the change in the density, dur to the formation of the solid phase, and the weight fractions of different binary systems was made. For validation purpose of the devleoped method, a pure normal paraffin (>95) is prepared from different mixtures of the following components, n-C6, n-C10, n-C20, n-C22, n-C24, n-C28, n-C32 andn-C36. A comparison between the standard method (UOP Method 46-64) and the developed method shows that the difference between the two methods is within 1-2wt
机译:油中的蜡含量和蜡的出现温度是模拟管道中蜡沉积曲线的重要因素。传统上使用标准丙酮方法(UOP方法46-64)或对该标准进行其他稍微修改的方法来确定油中的蜡含量。但是,为了确定不同温度下的蜡含量,必须进行几次试验。这被认为是耗时的。本文提出了一种新的方法/方法来确定不同温度下的油中蜡含量以及单次运行中蜡的沉淀温度。在这种方法中,在固相形成之前的密度变化与不同二元体系的重量分数之间建立了相关性。为了验证开发方法的有效性,从以下成分的不同混合物(n-C6,n-C10,n-C20,n-C22,n-C24,n-C28, n-C32和n-C36。标准方法(UOP方法46-64)与已开发方法之间的比较表明,两种方法之间的差异在1-2wt%之内

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