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Influence of metallic clusters on conduction in granular metals

机译:金属团簇对粒状金属导电性的影响

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Abstract: The process of electronic conduction in granular metals in the dielectric regime is being considered. The charging energy model of conduction in granular metals recently proposed in the literature, is extended to include the effect of the clustering of metallic component which takes place when metal-insulator transition is approached. The electrical conduction is modeled by a resistor lattice built from conductances, G$-ij$/ equals G$-0$/exp(-2$-chi$/s$- ij$/-E$-ij$/lkT), where $chi is the decay rate of the electron wave function in the insulator, k is Boltzmann's constant and s$-ij$/ and E$-ij$/ are intergrain separation and intergrain charging energy respectively. The process of clustering of metallic component is introduced as highly conductive bonds which appear in the lattice with average number of B bonds per lattice site. The critical path method is used to find the conductivity, $sigma@, of the model. Temperature dependence of, $sigma approximately equals exp$LB@-(T$- 1$//T)$+$HLF$/$RB in agreement with widely observed experiments is found. The temperature, T$-1$/, is found to decrease with B increasing i.e. when metal-insulator transition is approached in agreement with experiments reported for real granular metals. Numerical simulations of the model are performed. Quite good agreement between the critical path analysis and numerical data is found. !9
机译:摘要:正在研究介电状态下的粒状金属中的电子传导过程。最近在文献中提出的粒状金属中导电的充电能量模型被扩展到包括当接近金属-绝缘体转变时发生的金属组分的聚集效应。通过电导构建的电阻晶格来模拟电导率,G $ -ij $ /等于G $ -0 $ / exp(-2 $ -chi $ / s $-ij $ /-E $ -ij $ / lkT) ,其中$ chi是绝缘子中电子波函数的衰减率,k是玻尔兹曼常数,s $ -ij $ /和E $ -ij $ /分别是晶间分离和晶间充电能。金属成分的聚集过程是作为高导电键引入的,它出现在晶格中,每个晶格位点平均有B键。关键路径方法用于找到模型的电导率$ sigma @。发现与σ的温度依赖性大致等于exp $ LB @-(T $ -1 $ // T)$ + $ HLF $ / $ RB,这与广泛观察到的实验一致。发现温度T $ -1 $ /随着B的增加而降低,即,当金属-绝缘体转变达到与实粒金属报道的实验相一致时。对模型进行数值模拟。关键路径分析和数值数据之间找到了很好的一致性。 !9

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