Theoretical approach to modelling the low-barrier chemical reactions initiated by pulsed electron beam

摘要

A possibility to analyze low-barrier chemical reactions induced by electron beam is proposed within the framework of generalization of classical Kramers approach. A relationship for calculation of chemical reaction rate is received for potential barriers comparable with energy of system. It has been shown that results of our approach agree with results of dynamical modeling within 2% not only in the area of applicability of classical (Kramers) approach but also more widely.