High-molecular block copolymers of nitratemethyl and azidomethyl substituted oxetanes

机译：硝酸甲基和叠氮甲基取代的氧杂环丁烷的高分子嵌段共聚物

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The article presents the results of research of synthesis block copolymers nitratomethyl and azidomethyl-substituted oxetanes. 3- nitratomethyl-3-methyloxetane and 3,3-bis(azidome-thyl)oxetane, 3-azodomethyl-3-methyloxetane and 3,3-bis(azidomethyl)oxetane copolymers have been synthesized with different amount of monomer units. As a catalyst trialkylalumi-num-water system with 1:0,8 ratio was used. Copolymers were investigated by FTIR. differential scanning calorimetry, viscometry and elemental analysis.

机译：本文介绍了合成嵌段共聚物硝基甲基和叠氮甲基取代的氧杂环丁烷的研究结果。已经合成了具有不同数量的单体单元的3-硝基甲基-3-甲基氧杂环丁烷和3，3-双（叠氮基-乙基）氧杂环丁烷，3-偶氮甲基-3-甲基氧杂环丁烷和3，3-双（叠氮基甲基）氧杂环丁烷共聚物。作为催化剂，使用比例为1∶0.8的三烷基铝-水体系。通过FTIR研究共聚物。差示扫描量热法，粘度计和元素分析。

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《Seminar on new trends in research of energetic materials》|2018年|910-915|共6页
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T. I. Mukhametshin; A.V. Kostochko; V. A. Petrov; R.I. Sharipov; D.B. Vinogradov; PV. Bulatov;
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3,3-bis(azidomethyl)oxetane; 3- nitratomethyl -3-methyloxetane; 3-azodomethyl-3-methyloxetane; block copolymers; cationic ring opening polymerisation (CROP);

机译：3,3-双（叠氮甲基）氧杂环丁烷; 3-硝基甲基-3-甲基氧杂环丁烷; 3-偶氮甲基-3-甲基氧杂环丁烷;嵌段共聚物阳离子开环聚合（CROP）;

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专利

1. Synthesis and copolymerization of azidomethyl-substituted oxetanes: the morphology of statistical block copolymers [J] . Mukhametshin Timur I., Petrov Aleksei I., Kuznetsova Nina V., Chemistry of heterocyclic compounds . 2017,第6a7期

机译：氮甲基取代的氧化丙烷的合成与共聚：统计嵌段共聚物的形态
2. Synthesis and thermal decomposition of 3,3 '-bis-azidomethyl oxetane-3-azidomethyl-3 '-methyl oxetane random copolymer [J] . Zhang Chi, Li Jie, Luo Yunjun, Soft Materials . 2016,第1a4期

机译：3,3'-双叠氮基甲基氧杂环丁烷-3-叠氮基甲基-3'-甲基氧杂环丁烷无规共聚物的合成与热分解
3. Energy-Intensive Random Block Copolymers of 3,3-Bis (Nitratomethyl) Oxetane and 3-Azidomethyl-3-Methyloxetane [J] . Mukhametshin Timur I., Sharipov Rail I., Petrov Vladimir A., Propellants, Explosives, Pyrotechnics . 2018,第11期

机译：3,3-双（硝基甲基）氧杂环丁烷和3-氮杂甲基-3-甲基氧基乙烷的能量 - 强化随机嵌段共聚物
4. High-molecular block copolymers of nitratemethyl and azidomethyl substituted oxetanes [C] . T. I. Mukhametshin, A.V. Kostochko, V. A. Petrov, Seminar on new trends in research of energetic materials . 2018

机译：硝基甲基和氮杂甲基取代的氧扫描蛋白的高分子嵌段共聚物
5. The photophysics and molecular conformations of methoxy- and pyridine-substituted poly(phenylene vinylene) segmented block copolymers and bis-MSB derivatives in solution and thin film [D] . Kyllo, Erica Marie 2002

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6. Conductivity of Insulating Diblock Copolymer System Filled with Conductive Particles Having Different Affinities for Dissimilar Copolymer Blocks [O] . A.I. Chervanyov 2020

机译：绝缘二嵌段共聚物系统的电导率填充有具有不同亲和性共聚物嵌段的导电颗粒的导电颗粒
7. Polymerization of Substituted Acetylenes Using Well‐Defined Rhodium Complex Catalyst. Chirality Transfer and Amplification in Chiral‐Chiral Block and Random Copolymers [O] . Masahide Goto, Ayaka Nito, Yu Miyagi, 2019

机译：使用良好限定的铑配合物催化剂聚合取代的乙炔。手性 - 手性嵌段和随机共聚物中的手性转移和扩增
8. Characterization of Block Copolymers Based on Poly(3,3 -bis(ethoxymethyl)oxetane) and Other Novel Polyethers [R] . Hardenstine, K. E., Murphy, C. J., Jones, R. B., 1984

机译：基于聚（3,3-双（乙氧基甲基）氧杂环丁烷）和其他新型聚醚的嵌段共聚物的表征

High-molecular block copolymers of nitratemethyl and azidomethyl substituted oxetanes

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