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Synthesis of 5-3,6,7,10,11-pentakispentyloxytriphenylen-2-yloxypentyl Methacrylate and Its Mesomorphism Study

机译:甲基丙烯酸5-3,6,7,10,11-五akispentyloxytriphenylen-2-yloxypentyl甲基丙烯酸酯的合成及其同构研究

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摘要

A novel triphenylene-based discotic liquid crystal 5-3,6,7,10,11-pentakispentyloxytriphenylen-2-yloxypentyl methacrylate was successfully synthesized. Chemical structure of this compound was determined by H-NMR and FT-IR spectrum, and its mesomorphism was investigated under the guidance of differential scanning calorimeter (DSC) and polarizing optical microscopy (POM) method. This compound apparently exhibited a classical texture of columnar phase in the mesophase temperature. The double bond on the side chain made it possible for this compound to be a candidate of designing and synthesizing liquid crystal polymer.
机译:成功地合成了一种新型的基于三亚苯基的盘状液晶5-3,6,7,10,11-戊基戊氧基三苯甲基-2-基氧基戊基甲基丙烯酸酯。通过1 H-NMR和FT-IR光谱确定该化合物的化学结构,并在差示扫描量热仪(DSC)和偏振光学显微镜(POM)方法的指导下研究其同构。该化合物显然在中间相温度下显示出柱状相的经典织构。侧链上的双键使该化合物成为设计和合成液晶聚合物的候选者。

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