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The Investigation of Ozonolysis Reactions of Ethylene Using a Plug Flow Reactor and Gas Chromatography

机译:活塞流反应器和气相色谱法研究乙烯的臭氧分解反应

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A plug flow reactor (PFR) is designed and tested, and the products of ethylene (C_2H_4) ozonolysis reactions are investigated using a gas chromatography (GC). Fuel and oxidizer are supplied separately into this PFR assembly at low concentrations, such that the ozonolysis reactions are slow enough to be studied under room temperature and atmospheric pressure. Numerical simulations are conducted to assist the design of PFR and to determine the boundary conditions of this experiment. By changing the ozone (O_3) concentration in oxygen (O_2) stream, products of the C_2H_4 ozonolysis reactions are diagnosed to check any difference in the product components. Some important products of C_2H_4 ozonolysis reactions like H_2, CO_2 and H_2O are observed by GC. This PFR study is promising for a better understanding to the chemical kinetics of C_2H_4 ozonolysis reactions, which can improve the accuracy of numerical simulations including ozonolysis reactions.
机译:设计并测试了活塞流反应器(PFR),并使用气相色谱(GC)研究了乙烯(C_2H_4)臭氧分解反应的产物。燃料和氧化剂以低浓度单独供应到该PFR组件中,因此臭氧分解反应的速度足够慢,可以在室温和大气压下进行研究。进行了数值模拟,以辅助PFR的设计并确定该实验的边界条件。通过改变氧气(O_2)流中的臭氧(O_3)浓度,诊断出C_2H_4臭氧分解反应的产物,以检查产物成分中的任何差异。 GC观察到一些重要的C_2H_4臭氧分解反应产物,如H_2,CO_2和H_2O。这项PFR研究有望更好地了解C_2H_4臭氧分解反应的化学动力学,这可以提高包括臭氧分解反应在内的数值模拟的准确性。

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