Reaction of S,S'-dimethyl-N-nitroimidodithiocarbonate with nitroaminoguanidine

摘要

Reaction of S,S'-dimethyl-N-nitroimidodithiocarbonate with nitroaminoguanidine has been investigated. Surprisingly found that the nucleophilic substitution reaction proceeds with the substitution of the nitroimine group of S,S'-dimethyl-N-nitroimidodithiocarbonate instead of methylthio groups. The reaction product is nitroguanylhydrazone of S,S'-dimethyldithiocarbonate. Structure of the compound is established by X-ray diffraction, NMR spectroscopy, mass spectrometry and elemental analysis, as well as studied by FTIR and UV spectroscopy.