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Inkjet printing of nano-silver conductive lines on polyimide substrates

机译:在聚酰亚胺基材上喷墨印刷纳米银导线

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Microfabrication of electronic and mechanical structure at the submillimeter scale is typically a time-consuming and expensive process. Lithographic techniques for silicon micromachining, used to fabricate integrated circuits and MEMS, take several weeks to go from drawings to completed chips, and require expensive facilities and extreme processing conditions. Therefore, for speeding up the fabrication process and saving the materials, inkjet printing technology which multiple small volumes of metallic, semiconducting, or insulating material are expelled at computer-defined positions on subtracts has been adopted. Piezoelectric inkjet printhead is adopted as the dispensing injector in the study due to the lower temperature operation compared to the thermal bubble inkjet printhead. From the literature review it could be found out that such processes to date have been limited in terms of line width of the microstructure (i.e. resolution), electrical conductivity, and material property. Therefore, this study will aim at constructing an inkjet-fabrication system with the combination of a commercial printhead and a computer-controlled moving gantry stage. The fabricating method is expelling silver nanoparticle droplets with fixed quantity and accurate registration on flexible Polyimide (PI) substrates with different roughness additively to produce conductive lines with different line widths and resistances. Microflow visualization (μ-FV) has been performed to study the silver nanoparticle droplet ejected from a drop-on-demand piezoelectric inkjet printhead and the equilibrium line characteristic of the nano-silver droplet deposition on a PI substrate. The unipolar waveform with a frequency of 1000 Hz and an amplitude of 60 V has been adopted for ejecting the silver nanoparticle droplet with a solid content of 30%, surface tension of 30 mN/m and viscosity of 15 cps. The back pressure is modulated to prevent the formation of satellite droplets experimentally. The PI substrate was placed onto a computer-controlled three-axis moving stage capable of a movement accuracy of 30 μm. Therefore multiple prints of the nano-silver conductive lines have also been carried out based on the moving accuracy. The ejected droplets under various back pressures from - 1.6 kPa to -0.8 kPa have been observed. The deposited silver nanoparticle conductive lines with the inter-dot spacings from 90 μm to 140 μm have also been investigated. After the thermal treatment (sinter temperature of 200°C and sinter duration of 1 hour), the optical microscopic images of the deposited silver nanoparticle conductive lines with the inter-dot spacing from 20 μm to 40 μm before and after sintering have been obtained. For the first time, the quadruple prints of the silver nanoparticle conductive lines on the PI films have been investigated to observe the line widths and electrical resistances. The silver nanoparticle conductive lines with quadruple prints on the PI substrates have a line width of 500 μm and a resistance of 1.4 Ω per centimeter. The present results not only provide the relevant information to the researchers for accurate analyses, but also the adequate fluid properties to the engineers for various purposes. In this way the inkjet fabrication could be adopted in many other applications for mass production.
机译:亚毫米级的电子和机械结构的微细加工通常是耗时且昂贵的过程。用于制造集成电路和MEMS的硅微加工光刻技术,从图纸到完成的芯片需要花费数周的时间,并且需要昂贵的设备和极端的加工条件。因此,为了加快制造过程并节省材料,已经采用了喷墨打印技术,该技术将多个小量的金属,半导体或绝缘材料以减法数排到计算机定义的位置。由于与热气泡喷墨打印头相比,其较低的温度操作,因此在研究中采用了压电喷墨打印头作为点胶注射器。从文献综述中可以发现,迄今为止,这种方法在微观结构的线宽(即分辨率),电导率和材料性能方面受到限制。因此,本研究的目标是构建一个将商用打印头和计算机控制的移动龙门架相结合的喷墨制造系统。该制造方法是将具有固定量的银纳米颗粒液滴排出并在具有不同粗糙度的柔性聚酰亚胺(PI)基板上精确对准,以相加地产生具有不同线宽和电阻的导线。进行了微流可视化(μ-FV)以研究从按需滴压电喷墨打印头喷出的银纳米颗粒液滴以及PI基板上沉积的纳米银液滴的平衡线特性。已采用频率为1000 Hz,振幅为60 V的单极波形来喷射固含量为30%,表面张力为30 mN / m和粘度为15 cps的银纳米颗粒液滴。调节背压以防止实验中形成卫星液滴。将PI基板放置在计算机控制的三轴移动平台上,该平台的移动精度为30μm。因此,还基于移动精度对纳米银导线进行了多次印刷。观察到在-1.6 kPa至-0.8 kPa的各种背压下喷射的液滴。还研究了点间距为90μm至140μm的沉积银纳米颗粒导线。在热处理之后(烧结温度为200℃并且烧结持续时间为1小时),获得了在烧结之前和之后点间间距为20μm至40μm的沉积的银纳米颗粒导线的光学显微图像。首次研究了PI膜上银纳米颗粒导线的四重印刷,以观察线宽和电阻。 PI基板上具有四重印刷的银纳米粒子导线的线宽为500μm,每厘米的电阻为1.4Ω。目前的结果不仅为研究人员提供了相关信息以进行准确的分析,而且还为工程师提供了用于各种目的的足够的流体性质。以此方式,喷墨制造可以在许多其他应用中被采用以进行批量生产。

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