Ultrafast One-Photon (232 vs 266 nm) Bond-Selective Photochemistry of Bromoiodomethane (CH_2Brl) in Solution

摘要

Ultrafast broadband transient absorption spectra measured from the deep-ultraviolet to the near-infrared region following single-photon excitation of bromoiodomethane in acetonitrile at different wavelengths manifest chromophore -selective structural rearrangement and carbon-halogen bond dissociation in solution.