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The effect of ultraviolet radiation on silver nanowire transparent electrode based on flexible polymeric film substrate

机译:紫外线对基于柔性聚合物薄膜基底的银纳米线透明电极的影响

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The transparent electrode based on silver nanowire (AgNW) networks has emerged as an outstanding alternative of the electrode based on indium tin oxide (ITO) film in particular for flexible electronics. The polymeric films are popularly applied as flexible substrates and thus the electrode employing AgNWs and polymeric film is potential to be widely used in our daily life. However, the applications of transparent electrode nowadays are greatly limited by the unsatisfied long-term stability, which is accelerated by the ultraviolet (UV) radiation due to the inevitable light exposure. In this study, the effect of ultraviolet radiation on AgNW electrode fabricated on flexible polymeric film is comprehensively investigated. With long-term ultraviolet radiation, the change of sheet resistance (Rs) began with a small rise, followed by the sharp decrease and then the gradual increase. The morphology of AgNWs exposed to UV radiation was analyzed accordingly. Meantime, the degradation of polymeric film was also observed. The deformation of film surface was influenced by the shape of AgNW networks, and the increased roughness undermined the transmittance of whole electrode.
机译:基于银纳米线(AgNW)网络的透明电极已经成为基于铟锡氧化物(ITO)膜的电极的杰出替代品,特别是对于柔性电子产品。聚合物膜普遍用作柔性基底,因此采用AgNWs和聚合物膜的电极有可能在我们的日常生活中广泛使用。然而,由于不能避免的长期稳定性,如今的透明电极的应用受到极大的限制,长期稳定性由于不可避免的曝光而被紫外线(UV)辐射所加速。在这项研究中,全面研究了紫外线对在柔性聚合物膜上制备的AgNW电极的影响。随着长期的紫外线辐射,薄层电阻(Rs)的变化开始时出现小幅上升,然后急剧下降,然后逐渐上升。相应地分析了暴露于紫外线辐射的AgNW的形态。同时,还观察到聚合物膜的降解。薄膜表面的变形受AgNW网络形状的影响,并且粗糙度的增加破坏了整个电极的透射率。

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