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Evaluation of Protective Coatings for SOFC Interconnects

机译:SOFC互连保护涂层的评估

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Chromium poisoning is a widely recognized degradation process in solid oxide fuel cells (SOFC). Stainless steel interconnect plates, in direct contact with the cathode, have been identified as the major chromium source, raising a need for electrically conducting protective coatings for the interconnects. This work evaluates four different manganese-cobalt protective coatings manufactured on thin steel foils, made by three commercial companies and a research centre. Area specific resistance, coating microstructure, and chromium retention are compared. Measurements were done in a humid atmosphere over 1000 hours at 700 °C. An innovative measurement setup was used, in which the coated steel samples are stacked adjacent to thin palladium foils with a screen-printed lanthanum strontium cobalt layer, replicating an SOFC cathode. As a conclusion, TeerCoating Ltd's and Turbocoating S.p.A's coatings performed similar to the Sandvik Material Technology's cerium-cobalt reference coating, and could be employed as such in SOFC applications.
机译:铬中毒是固体氧化物燃料电池(SOFC)中公认的降解过程。与阴极直接接触的不锈钢互连板已被认为是主要的铬源,因此需要用于互连的导电保护涂层。这项工作评估了由三个商业公司和一个研究中心制造的在薄钢箔上制造的四种不同的锰钴保护涂层。比较了面积比电阻,涂层微观结构和铬保留率。在700°C的潮湿环境中进行1000小时的测量。使用了创新的测量设置,其中,将涂层的钢样品堆叠在具有丝网印刷镧锶钴钴层的薄钯箔附近,复制了SOFC阴极。结论是,TeerCoating Ltd.和Turbocoating S.p.A的涂层的性能与山特维克材料技术公司的铈钴参考涂层相似,可以在SOFC应用中使用。

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