Cu{sup}(2+) and Zn{sup}(2+) adsorption to synthetic iron oxides and natural iron ore powder

摘要

Cu{sup}(2+) and Zn{sup}(2+) adsorption onto the synthetic iron oxides prepared in laboratory including ferrihydrite (amorphous), goethite and hematite, and natural iron ore powder were investigated. The results showed that Cu{sup}(2+) and Zn{sup}(2+) adsorption onto the iron oxides: ferrihydrite, goethite, hematite and iron ore powder could be described by non-linear Langmuir, linear Freundlich, and Temkin models with significant correlation (R>p=0.7646, n=8, α<0.01). The amount of Cu{sup}(2+) and Zn{sup}(2+) adsorbed by synthetic iron oxides was more than that by natural iron ore powder, moreover, Cu{sup}(2+) and Zn{sup}(2+) adsorption onto the synthetic iron oxides was in order as follows: ferrihydrite>goethite>hematite, and the synthesized ferrihydrite was considered to be of the maximum adsorption capability (18.38mmol/mol Fe for Cu{sup}(2+) and 10.72mmol/mol Fe for Zn{sup}(2+), respectively), due to its amorphous structure based on the X-ray diffraction (XRD) analysis. Comparison with iron oxides extracted from the natural surface coatings collected in natural aquatic environments, the synthetic ferrihydrite in the present study could be more suitable than other iron oxides to substitute iron oxides in the natural surface coatings in aquatic environments to investigate the transport, transform and fate of metals in laboratory conditions.