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Exergy Efficiency Analysis of a Power-to-Methane System Coupling Water Electrolysis and Sabatier Reaction

机译:电力到甲烷系统耦合水电解和兔子反应的效率分析

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The seasonal and intermittent features result in the renewable power curtailment. Seasonal power storage is required to utilize the curtailed renewable power. Power-to-methane (PtM) systems coupling solid oxide electrolysis cell (SOEC) and Sabatier reactors offers an efficient and promising pathway to integrate the renewable power with the existing natural gas network. SOEC operates at a higher temperature and yet produce hydrogen or syngas with a controllable H_2/CO ratio with higher efficiency compared to low temperature electrolyzers. Besides, with the coupling of the SOEC and the Sabatier reactor, methane can be synthesized in one reactor from renewable energy. In this study, we firstly compared the power-to-hydrogen processes using the alkaline electrolysis cell (AEC), the proton exchange membrane electrolysis cell (PEMEC) and the SOEC. Exergy efficiency analysis is also carried out to distinguish the qualities of the heat, electricity and gaseous fuels. The results show the PtM system using SOEC is more efficient than those using the other electrolysis technologies at high current density due to lower polarization and better heat coupling. For SOEC, H_2O/CO_2 co-electrolysis coupling with methanation reactor exhibits a slightly lower exergy efficiency at low current density than H_2O electrolysis coupling Sabatier reactor, but exceeds at high current density. At the H_2O flow rate of 0.036 mol s~(-1) m~(-2) and H/C ratio of 5.5, a peak exergy efficiency of 75.66% is achieved at the current density of -5500 A m~(-2).
机译:季节性和间歇性功能导致可再生电力缩减。需要季节性蓄电量来利用缩减可再生能力。能量到甲烷(PTM)系统偶联固体氧化物电解槽(SOEC)和Sabatier反应器提供了一种有效和有希望的途径,可与现有的天然气网络集成可再生能力。 SOEC在较高的温度下操作,但与低温电解器相比,较高效率的可控H_2 / CO比具有氢气或合成气。此外,随着SOEC和易拟合反应器的偶联,可以在一个来自可再生能量的反应器中合成甲烷。在这项研究中,我们首先将使用碱性电解细胞(AEC),质子交换膜电解细胞(PEMEC)和SOEC进行了氢气过程。还开展了高度效率分析,以区分热量,电力和气体燃料的品质。结果表明,由于较低的偏振和更好的热耦合,使用SOEC使用SOEC的PTM系统比使用高电流密度的其他电解技术的系统更有效。对于SOEC,H_2O / CO_2与甲烷化合物反应器的共电解偶联在低电流密度下略低于H_2O电解耦合砂达反应器,但超过高电流密度。在0.036mol s〜(-1)m〜(-2)和h / c比的H_2o流速下,5.5的峰值低渗效率为75.66%,电流密度为-5500a m〜(-2 )。

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