High-efficiency flexible CdTe superstrate devices

摘要

Flexible, superstrate CdTe devices combine the advantages of a commercially demonstrated, low-cost manufacturing process with a lightweight, flexible form factor. Here, we present data on cell efficiencies greater than 16%, and the critical processing changes that have enabled recent efficiency increases. The devices in this study were made on Corning? Willow? Glass, which is a highly transparent, flexible, hermetic, and dimensionally stable substrate that can withstand high processing temperatures. To date, we have produced devices with several different combinations of front and back contacts on this glass and have found that it is compatible with most of our standard processing steps. One of our best devices to date has a certified efficiency of 16.2%, with a short-circuit current density (J) of 25.6 mA/cm, an open-circuit voltage of 820 mV, and a fill factor (FF) of 77.3%. The increased J in this cell is due to an improved sputtered CdS:O deposition process, and the high FF is due to a co-evaporated ZnTe:Cu back contact.