Synthesis and energetic properties of 5,5'-dinitrimino-3,3'-methylene-1H-1,2,4-triazole and selected nitrogen rich salts

摘要

The synthesis of 5,5'-dinitrimino-3,3'-methylene-1H-1,2,4-triazole (1) and selected nitrogen rich salts are presented. All compounds were fully characterized in terms of sensitivity and energetic properties. Besides a chemical characterization including multinuclear magnetic resonance study (~1H, ~(13)C, ~(14)N) and vibrational analysis (IR, Raman), X-Ray diffraction was performed. Thermal stability was performed using differential scanning calo-rimetry. Detonation parameters (EXPLO5 code) were calculated based on CBS-4M computed heats of formation. The presented compounds show excellent thermal stabilities and are therefore of interest for possible applications as HEDM.