首页> 外文会议>International conference on structural mechanics in reactor technology >EFFECT OF MECHANICAL STRESS ON THE MODES OF CORROSION OF ZIRCONIUM ALLOYS. THEORETICAL APPROACH
【24h】

EFFECT OF MECHANICAL STRESS ON THE MODES OF CORROSION OF ZIRCONIUM ALLOYS. THEORETICAL APPROACH

机译:机械应力对锆合金腐蚀方式的影响。理论方法

获取原文

摘要

The paper deals with two theoretical problems in Zr-alloys corrosion. The first task is aimed to predict effect of variation in alloy composition on susceptibility of the alloy to nodular corrosion. The effect may be due to a feedback between the concentration of alloying atoms in the oxide film and the rate of oxygen transfer through the oxide film. Redistribution of alloying elements near the oxide-metal interface during the development of nodules may occur as a result of the drift of alloying additives in the field of mechanical stress. The second task is directed to determine parametric dependences for transition in oxidation kinetics. The transition in oxide growth kinetics may depend on the properties of zirconium alloy and oxide film. Parametric criterion for the transition was derived in the framework of theoretical analysis. The analysis assumed minimization of mechanical energy in the system 'oxide film - metal' with taking into account possible formation of periodic structures at the oxide-metal interface.
机译:本文讨论了Zr合金腐蚀的两个理论问题。首要任务是预测合金成分变化对合金对球状腐蚀敏感性的影响。该效果可能是由于在氧化膜中合金原子的浓度与氧气通过氧化膜的传输速率之间的反馈所致。在结瘤形成过程中,由于机械应力领域中合金添加剂的漂移,可能会导致合金元素在氧化物-金属界面附近重新分布。第二项任务是确定氧化动力学转变的参数依赖性。氧化物生长动力学的转变可能取决于锆合金和氧化物膜的性质。过渡的参数标准是在理论分析的框架内得出的。该分析假设将“氧化物膜-金属”系统中的机械能降至最低,并考虑到可能在氧化物-金属界面形成周期性结构。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号