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Structure Characterization for Wood-PMMA Composite

机译:木材-PMMA复合材料的结构表征

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摘要

A new composite, wood-polymer composite, was fabricated by formation of poly (methyl methacrylate) in wood cellular structure. Methyl methacrylate (MMA) monomer and a few of 2,2'- azobisisobutyronitrile (AIBN) as an initiator, as well as several drops of pyrimidine as catalyst were first impregnated into wood porous structure under a pressure condition, and then initiated for thermal polymerization through a catalyst-thermal treatment. The structure of WoodPMMA Composite was characterized by SEM, FTIR, XRD, and its thermal stability was also examined. The results indicate that PMMA polymer generated in wood cellular structure as an amorphous form, and interacted with wood cell walls, resulting in chemical combination between them. The thermal stability of Wood-PMMA composite was higher than untreated wood under 450°C.
机译:通过在木质多孔结构中形成聚(甲基丙烯酸甲酯)来制造一种新的复合材料,即木材-聚合物复合材料。首先在压力条件下将甲基丙烯酸甲酯(MMA)单体和一些2,2'-偶氮二异丁腈(AIBN)作为引发剂以及几滴嘧啶作为催化剂浸渍到木材多孔结构中,然后引发进行热聚合通过催化剂热处理。用SEM,FTIR,XRD对WoodPMMA复合材料的结构进行了表征,并对其热稳定性进行了研究。结果表明,PMMA聚合物以无定形形式在木质细胞结构中生成,并与木质细胞壁相互作用,从而导致它们之间的化学结合。在450°C下,Wood-PMMA复合材料的热稳定性高于未处理的木材。

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