IMPROVING THE TECHNOLOGICAL PERFORMANCES OF ARGENTINIAN BALL CLAYS: A CASE STUDY FROM PATAGONIA, ARGENTINA

摘要

Innovation in the tilemaking ceramic industry is stressing properties like powder flowability, ability to toughen green tiles, so turning technological requirements of ball clays ever stricter in terms of plasticity, dispersion in water, rheological behavior, workability in the green state, refractoriness and firing colour. Technological performance of ball clays were improved by taking as benchmark the highest quality raw materials on the market. The mineralogy, plasticity, methylene blue index and ceramic response of the Patagonian ball clays are analogous to those of European clays, but improvement is needed to approach the highest quality materials. On this basis, the Frente A, Super, Puma, and Lote 8 deposits were selected and their characteristics enhanced by additions of highly plastic and white-firing corrective clays targeted on the benchmark. Porcelain stoneware formulations, containing improved ball clay mixes, were experimented at both laboratory and industrial scale. The improved ball clays behave like the best raw materials currently used, although modest changes occur in the mechanical properties, water absorption and whiteness of the fired products.