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CVD in Weakly Rarefied Rotating Disk Flows

机译:弱稀疏旋转盘流中的CVD

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CVD in a weakly rarefied rotating disk flow was numerically investigated by using the SPIN code modified by including slip boundary conditions for velocity, concentration and temperature, and thereby extending the capability of the code to describe weakly rarefied flows. A model reaction mechanism for silicon deposition, including the gas-phase decomposition reaction of silane to silylene and the surface reactions of silane and silylene, was used in order to demonstrate the rarefied gas effects. Results show that, by taking into account of the temperature slip, the deposition rate decreases from its value based on the continuum model, mainly due to either the decrease of the concentration of silylene, which is the dominant deposition species at high temperatures, or the decrease of the sticking coefficient of silane, which is the dominant deposition species at low temperatures. Compared to that of the temperature slip, the influence of the velocity and concentration slips on the deposition rate is negligible.
机译:通过使用SPIN代码对弱稀疏旋转盘流中的CVD进行了数值研究,该SPIN代码修改了速度,浓度和温度的滑移边界条件,从而扩展了该代码描述弱稀疏流的能力。为了证明稀有气体效应,使用了模型化的硅沉积反应机理,包括硅烷对甲硅烷基的气相分解反应以及硅烷与甲硅烷基的表面反应。结果表明,考虑到温度滑移,沉积速率从基于连续介质模型的值开始降低,这主要是由于作为高温下主要沉积物的亚甲硅浓度的降低或降低了硅烷的黏着系数,硅烷的黏着系数是低温下的主要沉积物。与温度滑移相比,速度和浓度滑移对沉积速率的影响可以忽略不计。

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