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Reduction Kinetics of a Natural Ilmenite by Graphite

机译:石墨对天然钛铁矿的还原动力学

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摘要

Reduction of Bama ilmenite concentrate containing 49.78 mass% TiO2 and 27.96 mass% total Fe by graphite was studied using thermogravimetric analysis system under argon gas ambient at elevated temperature. The reduction degree of Bama ilmenite enhanced with increasing temperature, the reaction rate varied with temperature and reduction time simultaneously. The phase transformation, the chemical composition, the microstructure and morphology of reduced samples were investigated by using X-ray diffraction, Scanning electron microscopy, Energy disperse spectroscopy respectively. The high impurities content of Bama ilmenite evidently bated the reduction of ilmenite. Forming the enrichment zone of manganese prevented complete reduction of Fe2+. The reduction products were mostly reduced iron, rutile, reduced rutiles, Ti3O5 and pseudobrookite solid solution. The reduction kinetics was also discussed. The results showed that the reduction temperature was a key factor to control reaction rate.
机译:在高温的氩气环境下,使用热重分析系统研究了石墨对含49.78质量%TiO2和27.96质量%总铁的巴马钛铁矿精矿的还原作用。巴马钛铁矿的还原度随温度的升高而提高,反应速率随温度和还原时间的变化而变化。通过X射线衍射,扫描电镜,能谱分析研究了还原后样品的相变,化学组成,微观结构和形貌。巴马钛铁矿的高杂质含量明显抑制了钛铁矿的还原。形成锰富集区阻止了Fe2 +的完全还原。还原产物主要是还原铁,金红石,还原金红石,Ti3O5和假板钛矿固溶体。还讨论了还原动力学。结果表明,还原温度是控制反应速率的关键因素。

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