Hydrometallurgical Processing of Rhenium-containing By-products of Lead Production

摘要

The results of research on recovery of ammonium perrhenate from by-products of lead production are presented in the article. For the first time in the world, rhenium marketable products were produced on lead plant of Kazakhstan. Distribution of rhenium in lead production has been studied.During oxidative agglomeration of lead charge, 67.43% rhenium is sublimated and at that, 67.27%rhenium is trapped by the dusts of a system of gas purification, out of them 6.21% is transferred into different solutions, 1.89% into slime and only 0.09% into exhaust.During agglomerate smelting, up to 72% of its rhenium is sublimated and condensed in the dusts also. At leaching stage of sulphate product under dusts processing by the method of sulphatization,15% of its content in the dusts is transferred into solution. The sorption method on the ionite AN-21 has been proposed for recovery of rhenium from the solutions of sulphatization. At the same time,rhenium recovery from the dusts into commodity was 13%.The method of direct hydrometallurgy leaching the dusts by solutions of sulphuric acid under presence of manganous concentrates, has been proposed as alternative method of recovery. This method has allowed increasing recovery of rhenium and other metals from the dusts into solution up to 90%～95%. Rhenium solvent extraction by TAA has been proposed for recovery of rhenium from the leaching solutions. At that, extraction of rhenium into marketable product from the dusts is above 75%.