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Western Xiamen Bay (China) Sediment Metal Ex-Situ Remediation Methodology Study

机译:厦门西湾(中国)沉积物金属异位修复方法学研究

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In this study, we carried out several sets of laboratory-based experimentsunder various conditions in order to develop technically feasible and cost effective ex-situsediment remediation techniques. The sediment for this study was collected from asewage sludge contaminated site in western Xiamen Bay, China, in July 2005. The mainfindings from this study include (1) low pH condition (pH < 5) and large solid-to-liquidratio (e.g., 1:50) increase metal extraction efficiency by EDTA-2Na, although theefficiency for each metal are different due to chemical properties of each metal andEDTA-2Na; (2) 0.20 M (NH_4)2C_2O_4 + 0.025 M EDTA combination with solid:liquidratio = 1:50 and 0.50 M NH_4Ac + 0.025 M EDTA combination with solid:liquid ratio =1:50 are the adoptable methods to extract metal contaminants with respect to extractionefficiency and economical cost; (3) using 0.010M SDS solution with solid:liquid ratio =1:20 should be avoided because it is much less effective in removal of metals fromsediments; (4) using 0.20 M H2_C_2O_4 solution under aeration with solid:liquid ratio = 1:50yields the best extraction efficiency for Cu (93%), Zn (89%), Cd (79%), Cr (45%) and Ni(66%). But, this method has very low extraction efficiency for Pb (3.4%); and (5) using0.025 M EDTA solution with aeration and solid:liquid ratio = 1:50 has ~73% extractionefficiency for Pb besides moderate to high extraction efficiencies for other metals (exceptfor Cr) ranging from 37% (Ni) to 94% (Cu). This study provides important and usefulinformation for sediment decontamination technology development.
机译:在这项研究中,我们进行了几组基于实验室的实验 在各种条件下进行开发,以实现技术上可行且具有成本效益的异地 沉积物修复技术。这项研究的沉积物是从一个 2005年7月,中国厦门湾西部的污水污泥污染现场。 这项研究的发现包括(1)低pH条件(pH <5)和较大的固液比 比例(例如1:50)可提高EDTA-2Na的金属萃取效率,尽管 每种金属的化学性质不同,每种金属的效率也不同。 EDTA-2Na; (2)0.20 M(NH_4)2C_2O_4 + 0.025 M EDTA与固体:液体的混合物 比例= 1:50和0.50 M NH_4Ac + 0.025 M EDTA组合,固液比= 对于提取而言,采用1:50的方法是提取金属污染物的方法 效率和经济成本; (3)使用0.010M SDS溶液,固液比= 应该避免使用1:20,因为从金属中去除金属的效率要低得多 沉积物(4)在曝气条件下使用0.20 M H2_C_2O_4溶液,固液比= 1:50 铜(93%),锌(89%),镉(79%),铬(45%)和镍的提取效率最高 (66%)。但是,该方法对铅的提取效率非常低(3.4%);和(5)使用 曝气量为0.025 M的EDTA溶液,固液比= 1:50,萃取率为〜73% Pb除其他金属的中到高提取效率外(除 Cr含量范围从37%(Ni)到94%(Cu)。这项研究提供了重要而有用的 沉积物净化技术发展的信息。

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