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Western Xiamen Bay (China) Sediment Metal Ex-Situ Remediation Methodology Study

机译:西部厦门湾(中国)沉积物金属前所修复方法研究

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In this study, we carried out several sets of laboratory-based experiments under various conditions in order to develop technically feasible and cost effective ex-situ sediment remediation techniques. The sediment for this study was collected from a sewage sludge contaminated site in western Xiamen Bay, China, in July 2005. The main findings from this study include (1) low pH condition (pH < 5) and large solid-to-liquid ratio (e.g., 1:50) increase metal extraction efficiency by EDTA-2Na, although the efficiency for each metal are different due to chemical properties of each metal and EDTA-2Na; (2) 0.20 M (NH_4)2C_2O_4 + 0.025 M EDTA combination with solid:liquid ratio = 1:50 and 0.50 M NH_4Ac + 0.025 M EDTA combination with solid:liquid ratio = 1:50 are the adoptable methods to extract metal contaminants with respect to extraction efficiency and economical cost; (3) using 0.010M SDS solution with solid:liquid ratio = 1:20 should be avoided because it is much less effective in removal of metals from sediments; (4) using 0.20 M H2_C_2O_4 solution under aeration with solid:liquid ratio = 1:50 yields the best extraction efficiency for Cu (93%), Zn (89%), Cd (79%), Cr (45%) and Ni (66%). But, this method has very low extraction efficiency for Pb (3.4%); and (5) using 0.025 M EDTA solution with aeration and solid:liquid ratio = 1:50 has ~73% extraction efficiency for Pb besides moderate to high extraction efficiencies for other metals (except for Cr) ranging from 37% (Ni) to 94% (Cu). This study provides important and useful information for sediment decontamination technology development.
机译:在这项研究中,我们在各种条件下进行了几套基于实验室的实验实验,以便在技术上可行和成本效益的前沉积物修复技术。 2005年7月,从中国西部湾湾污水污泥污染遗址收集了该研究的沉积物。本研究的主要发现包括(1)低pH条件(pH <5)和大型固体比例(例如,1:50)通过EDTA-2NA增加金属提取效率,尽管由于每个金属和EDTA-2NA的化学性质,每个金属的效率都不同; (2)0.20米(NH_4)2C_2O_4 + 0.025M EDTA与固体组合:液体比率= 1:50和0.50 M NH_4AC + 0.025M EDTA与固体组合:液体比率= 1:50是提取金属污染物的可采用方法尊重提取效率和经济成本; (3)使用固体的0.010M SDS溶液:应避免使用液体比率= 1:20,因为它在从沉积物中除去金属的效果要小得多; (4)使用0.20μmH2_C_2O_4溶液的固体:液体比率= 1:50产生Cu(93%),Zn(89%),Cd(79%),Cr(45%)和Ni的最佳提取效率(66%)。但是,这种方法对PB的提取效率非常低(3.4%); (5)使用0.025 m的EDTA溶液和固体:液体比率= 1:50,除了中度至高萃取效率(除了CR)范围为37%(Ni),Pb的提取效率= 1:50具有〜73%的提取效率。 94%(Cu)。本研究为沉积物净化技术开发提供了重要和有用的信息。

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