首页> 外文会议>International symposium on emerging technologies of pulping and papermaking;ISETPP >THE STUDY ON THE OPTIMIUM SYNTHESIS PROCESS OF AMPHOTERIC GELATIN USED AS PAPER DRY STRENGTH AGENT
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THE STUDY ON THE OPTIMIUM SYNTHESIS PROCESS OF AMPHOTERIC GELATIN USED AS PAPER DRY STRENGTH AGENT

机译:纸质干强度剂两性明胶的最佳合成工艺研究

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A graft copolymer was synthesized by copolymerization of gelatin with methylacryloxyethyl-trimethylammoniuM chloride (DMC), acrylamide (AM) and 2-acrylamido-2methyl propane sulfonic acid (AMPS). The copolymerization was conducted in aqueous solutions initiated by redox initiator. The product was a kind of amphoteric graft copolymer. The effect of reaction conditions, e.g., the concentration of monomers and initiator, the reaction time, the temperature, the pH as well as the total solid content on graft copolymerization, were discussed. The optimuM conditions were that the temperature was 50°C, the reaction time was 6h, the pH value was 7, the total solid content was 12%, the concentration of the initiator was 1.25%, the weight ratio of AM and DMc was 4: 1, the ratio of cationic monomer to anionic monomer was 1: 1.5, and the cationic monomers should be added into the system earlier than the anionic monomers. The existence of the amphoteric gelatin could be proved by the IR analysis of the graft copolymer. When the graft copolymer was used as a dry strength agent for bleached wheat straw pulp, the breaking length and burst index of the handsheets were remarkably improved.
机译:通过将明胶与甲基丙烯酰氧基乙基-三甲基铵氯化物(DMC),丙烯酰胺(AM)和2-丙烯酰胺基-2-甲基丙烷磺酸(AMPS)共聚来合成接枝共聚物。共聚在由氧化还原引发剂引发的水溶液中进行。该产物是一种两性接枝共聚物。讨论了反应条件的影响,例如单体和引发剂的浓度,反应时间,温度,pH值以及总固体含量对接枝共聚的影响。最适条件为温度为50°C,反应时间为6h,pH值为7,总固含量为12%,引发剂浓度为1.25%,AM与DMc的重量比为4 1:1,阳离子单体与阴离子单体的比例为1:1.5,并且阳离子单体应比阴离子单体更早地添加到系统中。两性明胶的存在可以通过接枝共聚物的IR分析来证明。当接枝共聚物用作漂白的麦草浆的干强度剂时,手抄纸的断裂长度和破裂指数显着提高。

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