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SYNTHESIS AND SINTERING OF YTTRIUM-DOPED BARIUM ZIRCONATE

机译:钇掺杂钡锆酸钡的合成与烧结

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Ba(Zr_(0.85)Y_(0.15))O_(3-δ) (BZY) has been synthesized by co-precipitation method. Powder x-ray diffraction patterns confirmed phase pure material formation at 1100°C. The average particle size of the 1100°C calcined powder was found to be -1μm. The nature of the powder was found to be softly agglomerated. Shrinkage behaviour of powder compacts has been studied. Effect of addition of different amounts of ZnO on the shrinkage behaviour and sintered density of BZY has also been studied. It was observed that addition of ZnO enhanced sintering, sintered density of more than 95 % TD was achieved by sintering at 1400°C. Study of sintering kinetics of powder compacts with 1 wt % ZnO and without ZnO has been carried out. Initial results show that different sintering mechanisms operate in these two materials. This is also supported by microstructural studies.
机译:BA(Zr_(0.85)Y_(0.15))O_(3-δ)(BZY)通过共沉淀法合成。粉末X射线衍射图案在1100℃下确认相纯材料形成。发现1100℃煅烧粉末的平均粒径为-1μm。发现粉末的性质被柔和地凝聚。研究了粉末压缩的收缩行为。还研究了添加不同量的ZnO对BZY的收缩行为和烧结密度的影响。观察到,通过在1400℃下烧结,通过烧结实现ZnO增强的烧结,烧结密度大于95%Td。已经进行了用1wt%ZnO和不含ZnO的粉末压块烧结动力学的研究。初始结果表明,不同的烧结机构在这两种材料中运行。这也得到了微观结构研究的支持。

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