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Preparation of α-Alumina-Supported Mesoporous Bentonite Membranes for Reverse Osmosis Desalination of Aqueous Solutions

机译:α-氧化铝负载的介孔膨润土膜的制备,用于水溶液的反渗透脱水

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In this work, mesoporous bentonite clay membranes approximately 2μm thick were prepared on porous α-alumina substrates by a sol-gel method. Nanosized clay particles were obtained from commercial Na-bentonite powders (Wyoming) by a process of sedimentation, washing, and freeze-drying. X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and nitrogen adsorption-desorptions (BET) were employed for membrane characterizations. The membranes were tested for reverse osmosis (RO) separation of a 0.1M NaCl solutions. Both water permeability and Na+ rejection rate of the supported membranes were comparable to that of the compacted thick membranes reported in the literature. However, due to the drastically reduced membrane thickness, water permeance and flux of the supported membranes were significantly higher than those of the compacted thick membranes.
机译:在这项工作中,通过溶胶 - 凝胶法在多孔α-氧化铝底物上制备约2μm厚的中孔膨润土粘土膜。通过沉积,洗涤和冷冻干燥的方法从商业Na-Bentonite粉末(Wyoming)获得纳米化粘土颗粒。 X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM)和氮吸附 - 去梳(BET)用于膜特征。测试膜的反渗透(RO)分离0.1M NaCl溶液。支撑膜的渗透性和Na +抑制率均可与文献中报道的压实厚膜的渗透性相当。然而,由于膜厚的巨大降低,负载膜的水渗透和通量显着高于压实厚膜的渗透性。

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