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Preparation of α-Alumina-Supported Mesoporous Bentonite Membranes for Reverse Osmosis Desalination of Aqueous Solutions

机译:用于水溶液反渗透脱盐的α-氧化铝负载介孔膨润土膜的制备

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In this work, mesoporous bentonite clay membranes approximately 2μm thick were prepared on porous α-alumina substrates by a sol-gel method. Nanosized clay particles were obtained from commercial Na-bentonite powders (Wyoming) by a process of sedimentation, washing, and freeze-drying. X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and nitrogen adsorption-desorptions (BET) were employed for membrane characterizations. The membranes were tested for reverse osmosis (RO) separation of a 0.1M NaCl solutions. Both water permeability and Na+ rejection rate of the supported membranes were comparable to that of the compacted thick membranes reported in the literature. However, due to the drastically reduced membrane thickness, water permeance and flux of the supported membranes were significantly higher than those of the compacted thick membranes.
机译:在这项工作中,通过溶胶-凝胶法在多孔α-氧化铝基底上制备了约2μm厚的中孔膨润土粘土膜。通过沉降,洗涤和冷冻干燥的方法从市售钠膨润土粉末(怀俄明州)获得纳米尺寸的粘土颗粒。 X射线衍射(XRD),扫描电子显微镜(SEM),透射电子显微镜(TEM)和氮吸附-脱附(BET)用于膜表征。测试了膜的0.1M NaCl溶液的反渗透(RO)分离。支撑膜的透水性和Na +截留率均与文献报道的压实厚膜相当。但是,由于膜的厚度大大减小,因此被支撑的膜的透水率和通量明显高于压实的厚膜。

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