首页> 外文会议>69th NLGI Annual Meeting Oct 27-31, 2002 Coronado, California >Pour Point Depressants and their Impact on the Low Temperature Properties of Greases
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Pour Point Depressants and their Impact on the Low Temperature Properties of Greases

机译:降凝剂及其对油脂低温性能的影响

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The use of pour point depressants to lower the pour point of engine oils is well known in the literature and the types of pour points depressants are varied. Typically these highly viscous or solid polymers are delivered in oils or some other type of solvent. They are extremely effective in modifying the pour point of oils with treat rates generally less than 0.5 per cent by weight. However, the amount of pour point depressant used will vary according to the base oil type, concentration of the polymer in the oil, the type of polymer and the degree of pour point correction desired. Greases are also required to operate at extreme temperatures and due to their rheology, low temperatures can have a profound effect on their ability to properly function. Greases that meet the NLGI GC/LB specification for the D4693 (Standard Test Method for Low-Temperature Torque of Grease-Lubricated Wheel Bearings) must pass the low temperature torque test at -40°C. The majority of manufactured greases are made with mineral oils that are thickened with lithium 12-hydroxystearate or lithium stearate and they may not pass this test. One method to improve the low temperature properties for these greases is to use synthetic polyalphaolefin (PAO) base stocks. However, the disadvantage of using PAOs is they add cost to the finished grease. Typically, paraffinic mineral oils are the least expensive of oils to use, and therefore, are preferred for their cost savings, but they aggravate this low temperature problem. There have been questions whether the addition of pour point depressants to lithium stearate type greases, which contain high VI paraffinic base oils, would improve the low temperature performance of the grease while still maintaining its cost effectiveness by using the paraffinic oil. This paper will present the results of our study on the effects that three types of pour point depressants had on paraffinic and naphthenic oil based greases when they were evaluated in a Low Temperature Oscillation Rheometry Test. The results will show that the pour point depressant has no effect on the low temperature properties of paraffinic oil based greases regardless of grease grade. Changing from a paraffinic to naphthenic base oil had more effect on the low temperature properties of the finished grease than by the addition of pour point depressants.
机译:在文献中使用降凝剂来降低机油的凝点是众所周知的,并且降凝剂的类型是多种多样的。通常,这些高粘度或固体聚合物以油或某种其他类型的溶剂形式输送。它们在改变油的倾点方面非常有效,处理率通常低于0.5%(重量)。但是,降凝剂的用量将根据基础油类型,油中聚合物的浓度,聚合物的类型和所需的倾点校正程度而变化。润滑脂也需要在极端温度下运行,由于其流变性,低温可能会对润滑脂的正常功能产生深远影响。符合NLGI GC / LB D4693规范(润滑脂润滑车轮轴承低温扭矩的标准测试方法)的润滑脂必须通过-40°C的低温扭矩测试。大多数制造的润滑脂都是用矿物油制成的,这些矿物油会用12-羟基硬脂酸锂或硬脂酸锂增稠,并且它们可能无法通过该测试。改善这些润滑脂的低温性能的一种方法是使用合成聚α-烯烃(PAO)基础油。但是,使用PAO的缺点是它们会增加成品油脂的成本。通常,链烷烃矿物油是最便宜的油,因此因节省成本而被优选,但加剧了这种低温问题。一直存在疑问,在高VI链烷烃基油的硬脂酸锂类润滑脂中添加降凝剂是否会改善润滑脂的低温性能,同时仍通过使用链烷烃油保持其成本效益。本文将介绍我们在低温振荡流变试验中评估的三种降凝剂对链烷烃和环烷油基润滑脂的影响的研究结果。结果表明,倾点降低剂对石蜡油基润滑脂的低温性能没有影响,而与润滑脂等级无关。与添加倾点下降剂相比,从链烷烃基油改为环烷烃基油对最终润滑脂的低温性能影响更大。

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