ADVANCES IN LIVING FREE-RADICAL POLYMERIZATION

摘要

In recent years, living free radical polymerization has become a robust route to synthesize novel architectural polymers with well-defined molecular structure and narrow polydispersity. The most studies on living free radical polymerization are focused on the areas of nitroxide-mediated free radical polymerization (SFRP), atom transfer radical polymerization (ATRP) using various transition-metal complexes and reversible addition fragmentation chain transfer (RAFT) process.