New atmospheric leach process for copper sulphide ores and concentrates

摘要

Over the years, numerous hydrometallurgical processes have been proposed as an alternative or complement to smelters for the treatment of copper concentrates. Most of these initiatives met with limited success. Bioleaching is applied commercially for secondary copper minerals heaps and dumps, and bacterial leaching processes are being developed for copper concentrates, although industrial application is still years away. More recently developed processes usually include pressure leaching and/or ultrafine grinding. This paper propose a new leach process to treat copper sulphide ores or concentrates: the process operates under atmospheric pressure and uses limited concentrations of ferric sulphate as oxidant; the key to the prcess is the regeneration of the ferric ion, which can be effected in-situ (direct process) or ex-situ (indirect process) using SO_2/O_2. Examples are presented for the treatment of copper concentrates by agitation leach and of copper ores by heap leaching. Application of the process to copper gold ores and chalcopyrite concentrates is also discussed.