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Determination of Onset Point of Asphaltene Deposition During Solvent Stimulated Oil Recovery Processes

机译:溶剂刺激采油过程中沥青质沉积起始点的确定

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The problem of asphaltene deposition in oil production, specially in EOR (enhanced oil recovery) processes is serious. The deposited asphaltenes blocked the reservoir pores and greatly reduced the recovery rate. In order to solve this problem, it is necessary to investigate the mechanism of asphaltene deposition, to determine the onset point, and to find the factors affecting the depositional process. In this work, the viscosity and electrical conductance of oil-solvent mixtures were determined for detecting the onset point of asphaltene deposition for Shengli, Liaohe, ad Shanjiasi crude oils. It is found experimentally that the viscosity of the oil-solvent system decreases with the addition of heptane, but there is a knee point on the curve which corresponds to the onset point of asphaltene deposition. When toluene is used as a solvent, there is no such knee point. The experiments indicated also that with the addition of heptane, the electrical conductance of the system rises at first and then falls. On the curve's first derivative, a maximum appears and can be defined as the onset point of asphaltenes deposition; there is no such maximum in most cases when toluene is used as a solvent. The data obtained by these two methods are slightly different, but they correlate well. It is further found that the onset of asphaltene deposition in crude oil occurs earlier than in its residue, indicating that the colloidal system of crude oil is less stable than that of its residue. Furthermore, it seems that the sulfur content of the oil exhibits an important influence on the stability of the colloidal system and the onset point of the asphaltene deposition. The electrical conductance method is more sensitive and less time-consuming than the viscosity method for the determination of the onset point of asphaltene deposition.
机译:在石油生产中,特别是在EOR(强化采油)工艺中,沥青质沉积的问题非常严重。沉积的沥青质堵塞了储层孔隙,大大降低了采收率。为了解决这个问题,有必要研究沥青质沉积的机理,确定起始点,并找出影响沉积过程的因素。在这项工作中,确定了油-溶剂混合物的粘度和电导率,以检测胜利,辽河和山家寺原油的沥青质沉积起始点。通过实验发现,油溶剂体系的粘度随庚烷的添加而降低,但是曲线上存在一个拐点,该拐点与沥青质沉积的开始点相对应。当使用甲苯作为溶剂时,没有这种拐点。实验还表明,随着庚烷的添加,系统的电导率先上升然后下降。在曲线的一阶导数上,出现了一个最大值,可以将其定义为沥青质沉积的起始点。当使用甲苯作为溶剂时,在大多数情况下没有这样的最大值。通过这两种方法获得的数据略有不同,但是它们之间具有很好的相关性。进一步发现,沥青质在原油中的沉积发生早于其残余物中的沉积,这表明原油的胶体体系比其残余物的胶体体系不稳定。此外,似乎油中的硫含量对胶体系统的稳定性和沥青质沉积的开始点表现出重要的影响。用于确定沥青质沉积起始点的电导方法比粘度方法更灵敏且耗时更少。

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