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Particle-level and volume-averaged treament of compacted-powder combustion synthesis

机译:密实粉燃烧合成的颗粒级和体积平均法

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The propagation-mode, compacted-powder combustion synthesis of intermetallics is analyzed through a combined particle-level/specimen-level treatment. The specimen-level treatment is based on the local volumeaveraged conservation equations for species and energy. The particle-level treatment considers a uniform temperature, the formation of products through a diffusioncontrolled heterogeneous reaction, and allows for melting of the product assuming a distinct interface between the phases. An experiment is performed with the aluminumtitanium system with a 3-1 stoichiometry. The temperature distribution and the combustion front speed are measured and the extent of conversion and uniformity of the final product are determined using electron microscopy.
机译:通过结合颗粒级/样品级处理,分析了金属间化合物的传播模式,压实粉末燃烧合成。标本级处理基于物种和能量的局部体积平均守恒方程。颗粒级处理考虑了均匀的温度,通过扩散控制的异相反应形成了产物,并假设各相之间存在明显的界面,从而允许产物熔融。实验是用化学计量比为3-1的铝钛系统进行的。测量温度分布和燃烧前沿速度,并使用电子显微镜确定最终产物的转化程度和均匀性。

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