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THE PRECISION OF DYNAMIC OSCILLATORY MEASUREMENTS

机译:动态振荡测量的精度

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This paper shows that, for isotropic polymers, oscillatory measurements in constant strain provide improved precision at higher frequencies while measurements in constant stress provide improved precision at lower frequencies. This is important as low frequency data is often used to estimate zero-shear viscosity [which correlates with molecular weight]. The "between-sample" and "within-sample" components of the total variation are determined for PDMS and HDPE. Modelling attempts are discussed.
机译:本文表明,对于各向同性聚合物,在恒定应变下的振荡测量可以在较高频率下提高精度,而在恒定应力下进行的测量则可以在较低频率下提高精度。这一点很重要,因为低频数据通常用于估计零剪切粘度(与分子量相关)。对于PDMS和HDPE,确定总变化的“样本间”和“样本内”分量。讨论了建模尝试。

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