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Damage to copper mirrors by high-power CO2 laser radiation,

机译:大功率CO2激光辐射会损坏铜镜,

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Abstract: A focused, cw CO$-2$/ laser is used to irradiate polished Cu mirrors at power densities near 40 kW/cm$+2$/. Uncoated mirrors and mirrors having a reflection-enhancing Au coating with a protective Y$-2$/O$-3$/ layer are tested. During irradiation in-situ measurements of the temperature distribution in the surface are made and the morphology is monitored by interferometry. Chemical changes are determined by ex-situ x-ray photoemission and scanning Auger measurements. Damage to uncoated mirrors is connected with irreversible deformation, an increase in thermal gradients under irradiation (attributable to increased absorption), and oxidation of the surface layer, with formation of Cu$-2$/O and CuO. While the whole surface becomes oxidized, the effect is strongest in the laser focus, where an enhanced carbon content is also found. Similar thermal and morphological changes occur in coated mirrors under analogous irradiation conditions, but the relatively inert Y$- 2$/O$-3$/ protective layer is not chemically changed. Structural changes are present in the surface and may contribute to the changed absorption. !5
机译:摘要:使用聚焦的连续CO $ -2 $ /激光照射功率密度接近40 kW / cm $ + 2 $ /的抛光铜镜。测试了未镀膜的镜和具有反射性Au涂层并具有Y $ -2 $ / O $ -3 $ /保护层的反射镜。在辐照期间,对表面中的温度分布进行原位测量,并通过干涉测量法监测形态。化学变化是通过异位X射线光发射和扫描俄歇(Auger)测量来确定的。未镀膜反射镜的损坏与不可逆的变形,辐射下的热梯度增加(归因于吸收增加)以及表面层的氧化有关,形成Cu $ -2 $ / O和CuO。虽然整个表面都被氧化,但在激光焦点处效果最强,在该处还发现碳含量增加。在类似的辐照条件下,镀膜反射镜会发生类似的热和形态变化,但是相对惰性的Y $ -2 $ / O $ -3 $ /保护层不会发生化学变化。表面上存在结构变化,并且可能导致吸收变化。 !5

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