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Cadmium selenide quantum dot doping of organic-inorganic hybrid materials derived by sol-gel processing

机译:溶胶-凝胶法制得的有机无机杂化材料硒化镉量子点掺杂

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Nanosized phenyl-capped CdSe particles (quantum dots) were isolated, after preparation inside reversed micelles present in AOT/H/sub 2/O/heptane, and then successfully redispersed in amine-functionalised ormosils derived from 3-aminopropyl(trimethoxy)silane (i.e. SA). Doped ormosils were formed into films of a few /spl mu/m thickness or small bulk samples. Host ormosils were structurally characterised by means of absorption spectroscopy, in the near- and mid-infrared ranges, and by /sup 29/Si and /sup 13/C solid state nuclear magnetic resonance (NMR) spectroscopy. Doped ormosils were prepared and investigated via visible spectroscopy. The size of CdSe particles dispersed into the aminosrmosil hosts was calculated using the effective mass model.
机译:分离纳米化苯基 - 封端的CdSe颗粒(量子点),在AOT / h / sub 2 / O /庚烷中存在的反向胶束内,然后在衍生自3-氨基丙基(三甲氧基)硅烷(即sa)。将掺杂的Ormosils形成为少数/分/ m厚度或小散装样品的薄膜。宿主Ormosils通过吸收光谱在近红外线范围内的吸收光谱和/ sup 29 / si和/ sup 13 / c固态核磁共振(NMR)光谱法来结构表征。通过可见光光谱制备并研究掺杂的或研究。使用有效质量模型计算分散到氨基核苷宿主中的CDSE颗粒的尺寸。

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