Nonresonant two-photon pulsed field ionization studies of organosulfur molecules and radicals

摘要

Abstract: Threshold photoelectron (PE) spectra for CH$-3$/SH, CH$-3$/S, and SH have been measured using the nonresonant two-photon pulse field ionization (N2P-PFI) technique. The rotationally resolved N2P-PFI-PE spectrum obtained for SH indicates that photoionization dynamics favors the rotational angular momentum change $Delta@N $LS 0 with the $Delta@N value up to $MIN@3.!51