首页> 外文会议>International Solvent Extraction Conference, Jul, 1999, Catalunya (Spain) >TAILOR-MADE AROMATIC CAGE COMPOUNDS AS TOOLS FOR SELECTIVE SOLVENT EXTRACTION OF METAL IONS
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TAILOR-MADE AROMATIC CAGE COMPOUNDS AS TOOLS FOR SELECTIVE SOLVENT EXTRACTION OF METAL IONS

机译:量身定制的芳族笼状化合物,作为金属离子选择性溶剂萃取的工具

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摘要

Differently functionalized aromatic cage compounds were synthesized and investigated in view of their extraction properties toward metal ions. The compounds show a pronounced selectivity for Ag(Ⅰ) over various hard and soft metal ions. The extraction efficiency of Ag(Ⅰ) strongly depends on the extractant structure and is controlled by different coordination patterns. Molecular modeling calculations of the complex structures allow the interpretation of the experimental results.
机译:考虑到它们对金属离子的萃取性能,合成并研究了不同功能的芳香族笼状化合物。该化合物对各种硬金属和软金属离子均具有明显的对Ag(Ⅰ)的选择性。 Ag(Ⅰ)的萃取效率在很大程度上取决于萃取剂的结构,并受不同配位模式的控制。复杂结构的分子建模计算可以解释实验结果。

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