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Kinetic Study and Optimum Control of the Ozone/UVProcess Measuring Hydrogen Peroxide Formed In-situ

机译:臭氧/紫外线法原位形成过氧化氢的动力学研究与最佳控制

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This study was conducted to develop the kinetic model of ozone/UVrnprocess monitoring the trend of hydrogen peroxide formed in-situ. Arnspecifically devised setup, which could continuously measure thernconcentration of hydrogen peroxide as low as 10 μg/L, was used.rnFrom this kinetic study, it was possible to determine the UV intensityrn(Io) of photo-reactor and the quantum yields (ΦO3 and Φper) of ozonernand hydrogen peroxide and to calculate the hydroxyl radical (OH°)rnconcentrations.rnThe optimum ozone dose was also investigated at the fixed UV dosernusing the removal rate of UV absorbance at 254nm (A254) in source ofrndinking water. The result showed that the continuous monitoring ofrnhydrogen peroxide formed in-situ in ozone/UV process could be usedrnas an important tool to operate the ozone/UV process at the optimumrncondition.
机译:进行该研究以开发臭氧/ UVrn过程的动力学模型,以监测原位形成的过氧化氢的趋势。使用专门设计的装置,该装置可以连续测量低至10μg/ L的过氧化氢浓度。rn从该动力学研究中,可以确定光反应器的UV强度(Io)和量子产率(ΦO3和臭氧和过氧化氢的浓度Φper),并计算出羟基自由基(OH°)的浓度。在固定紫外线剂量下,还利用饮用水中254nm(A254)的紫外线吸收率,研究了最佳臭氧剂量。结果表明,对臭氧/紫外光过程中原位形成的过氧化氢进行连续监测可作为在最佳条件下操作臭氧/紫外光过程的重要工具。

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