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STUDY OF THE THERMAL BEHAVIOR OF Pittosporum undulatum

机译:钝角云芝热行为的研究

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摘要

Sweet pittosporum (Pittosporum undulatum) is native to eastern parts of Australia. It is a tree growing to 15m tall with wavy (undulating) leaf edges and also has attractive fragrant flowers, sweet pittosporum. This tree has been introduced widely as an ornamental plant to North America, southern Brazil and also in Africa [1]. It is known as an invader of many tropical and subtropical mountain forests and in warm temperate regions of both hemispheres and many islands. The fruits have diameter among 1 and 1.5 cm and are orange capsules when ripe, sticky and possess a strong odour [2].In this work, we report on the extraction of the Pittosporum undulatum oil was carried out and characterization by gas chromatography. The composition of in nature of this oil indicates that there is a predominance of unsaturated fatty acids.TG/DTG curves of Pittosporum undulatum oil, with sample mass of 5mg, aluminum crucible, heating rate of 20℃ min~(-1) was obtained and the TG profile of this oil under nitrogen gas purge show that the first loss occur around 236℃ with one only mass loss, with loss of 99.60%. To analysis under oxygen gas purge, from DTG curve, the thermal decomposition occurs in five stages, between 220 and 550℃. The mass losses of the stages of thermal decomposition are: 25.55% (220 -312℃); 24.71% (312 -356℃); 14.52% (356 -398℃); 18.71% (398 -460℃) and 15.16% (460 - 550℃). As conclusion, it was possible, from TG and DTG curves establish the behavior under several atmospheres of the thermal decomposition of this oil.
机译:甜pittosporum(Pittosporum undulatum)原产于澳大利亚东部。它是一棵长至15m高的树,叶片边缘呈波浪形(波浪状),还开出迷人的芬芳花朵,甜美的pittosporum。该树已被广泛用作北美,巴西南部以及非洲的观赏植物[1]。它被认为是许多热带和亚热带山区森林以及半球和许多岛屿的温带温带地区的入侵者。果实的直径在1到1.5厘米之间,成熟时呈橙色胶囊,有粘性且有强烈的气味[2]。在这项工作中,我们报道了云芝Pittosporum undulatum油的提取并通过气相色谱法进行了表征。该油的自然成分表明存在大量的不饱和脂肪酸。样品质量为5mg,铝坩埚,加热速率为20℃min〜(-1)的云芝Pittosporum undulatum油的TG / DTG曲线。并且该油在氮气吹扫下的TG曲线表明,第一次损失发生在236℃左右,仅有一个质量损失,损失率为99.60%。为了进行氧气吹扫分析,根据DTG曲线,热分解发生在220至550℃的五个阶段。热分解阶段的质量损失为:25.55%(220 -312℃); 24.71%(312 -356℃); 14.52%(356 -398℃); 18.71%(398 -460℃)和15.16%(460-550℃)。结论是,有可能从TG和DTG曲线确定该油在几种气氛下的热分解行为。

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