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Innovative techniques in superconducting powders synthesis and their influence on material processing

机译:超导粉末合成的创新技术及其对材料加工的影响

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摘要

The discovery of superconducting oxides with a critical temperature above the boiling point of nitrogen has led to an enormous scientific and practical interest over the last decade. As a consequence, numerous approaches have been tried to synthesize products as pure as possible with optimal morphology and physical properties [1]. The most conventional method is the 'ceramic' technique [2], which involves mixing, grinding and heating of powders of metal oxides and carbonates. This technique requires multiple grindings and prolonged thermal treatment at high temepratures to achieve complete reaction since the formation of the superconducting phase proceeds via diffusion in the solid state. To achieve better mixing of the initial products, many chemical preparation techniques [3] for precursors have been developed (coprecipitation-filtration [4,5], sol-gel [6,7], spray-drying [8]) in which the reagents are mixed at a molecular level in solution and should therefore lead to more homogeneous end products that can be prepared at lower temperatures and/or in shorter times. Moreover, chemical precursors tend to be more suitable for making various shapes such as films, fibres, wires...
机译:在过去的十年中,临界温度高于氮气沸点的超导氧化物的发现引起了巨大的科学和实践兴趣。结果,尝试了许多方法来合成具有最佳形态和物理特性的尽可能纯的产品[1]。最常规的方法是“陶瓷”技术[2],该技术涉及金属氧化物和碳酸盐粉末的混合,研磨和加热。由于超导相的形成是通过固态扩散进行的,因此该技术需要在高温度下进行多次研磨和长时间的热处理以实现完全反应。为了更好地混合初始产品,已经开发了许多前体化学制备技术[3](共沉淀过滤[4,5],溶胶-凝胶[6,7],喷雾干燥[8]),其中试剂在溶液中以分子水平混合,因此应导致可以在较低温度和/或较短时间内制备的均质最终产品。此外,化学前体往往更适合于制造各种形状,例如薄膜,纤维,金属丝...

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