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GC/MS Analysis of PAHs in the Atmosphere Surrounding Refuse Incineration Plant from Beijing, China

机译:北京大气垃圾焚烧厂中多环芳烃的GC / MS分析

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Polycyclic aromatic hydrocarbons (PAHs), the most extensively distributed cancer-inducing materials in the world, have been haunting mankind as health killers for several decades. Due to their intimacy to the daily life of human beings, it is vital to attach importance on its monitoring and detection. In this paper, seven samples had been collected from the atmosphere surrounding the waste incineration plant. Pre-treatment by soxhlet extraction, silica gel column for purification, GC/MS for separation and determination were undertaken. Efforts also had been made to optimize purification column, the results showed silica gel column was the best choice. In this way, the average recovery rate of 16 PAHs were distributed between 55~107% and the linear correlation coefficient were between 0.9822~0.9995. After analysis of the real samples, it's found that 3 rings and 4 rings were mainly existed in the gas phase, of which Philippines had the highest content. Therefore, this method was very suitable for monitoring emissions of PAHs from the waste incineration facilities.
机译:多环芳烃(PAHs)是世界上分布最广泛的致癌物质,几十年来一直困扰着人类作为健康的杀手。由于它们与人类的日常生活密切相关,因此必须重视对其的监视和检测。本文从垃圾焚烧厂周围的大气中收集了七个样品。进行了索氏提取的预处理,硅胶柱的纯化,GC / MS的分离和测定。还进行了优化纯化柱的努力,结果表明硅胶柱是最佳选择。这样,16种多环芳烃的平均回收率分布在55〜107%之间,线性相关系数在0.9822〜0.9995之间。对实际样品进行分析后发现,气相中主要存在3个环和4个环,其中菲律宾含量最高。因此,该方法非常适合监测废物焚烧设施中PAHs的排放。

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