POLY(2-BUTYNE-1,4-DIYL)S AS PRECURSORS TO NOVEL SUBSTITUTED POLY ACETYLENES

机译：新型取代聚乙炔的前体聚（2-BUTYNE-1,4-DIYL）S

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Thermally-induced polymerization of 1,4-diphenyl-1,2,3-butatriene affords poly(1,4-diphenyl-2-butyne-1,4-diyl) as a soluble high molecular weight material. Structure is characterized by ~(13)C and vibrational spectroscopy. When treated with base, this material rearranges to a soluble red poly (acetylene) with a unique substitution pattern.

机译：1，4-二苯基-1，2，3-丁三烯的热诱导聚合得到作为可溶性高分子量材料的聚（1，4-二苯基-2-丁炔-1，4-二基）。结构的特征在于〜（13）C和振动光谱。当用碱处理时，该材料重新排列成具有独特取代图案的可溶性红色聚乙炔。

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来源
《Electrical, optical, and magnetic properties of organic solid-state materials IV》|1997年|725-732|共8页
会议地点 Boston MA(US)
作者
STEVEN K. POLLACK; ASHEBIR FISEHA;
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作者单位

Department of Chemistry and the Polymer Science and Engineering Program, Howard University, Washington, DC 20059;

Department of Chemistry and the Polymer Science and Engineering Program, Howard University, Washington, DC 20059;

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原文格式 PDF
正文语种 eng
中图分类有机质材料;
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专利

1. Butatriene-based polymer chemistry. 3. New route to substituted poly(acetylene)s through the base-catalyzed rearrangement of poly(2-butyne-1,4-diyl)s [J] . Pollack SK., Fiseha A. Macromolecules . 1998,第6期

机译：基于丁三烯的聚合物化学。 3.通过碱催化的聚（2-丁炔-1,4-二基）s重排反应来取代聚（乙炔）的新途径
2. Photooxidative stability of substituted poly(phenylene vinylene) (PPV) and poly(phenylene acetylene) (PPA) [J] . Cumpston BH., Jensen KF. Journal of Applied Polymer Science . 1998,第12期

机译：取代的聚苯乙炔（PPV）和聚苯乙炔（PPA）的光氧化稳定性
3. Langmuir-Blodgett mono- and multilayers of (di)alkoxy-substituted poly(p-phenylenevinylene) precursor polymers. 1. Langmuir monolayers of homo- and copolymers of (di)alkoxy-substituted precursor PPVs [J] . Hagting J.G., Sinkovics K., Vorenkamp E.J., Macromolecules . 1999,第12期

机译：（二）烷氧基取代的聚（对亚苯基亚乙烯基）前体聚合物的Langmuir-Blodgett单和多层。 1.（二）烷氧基取代的前体PPV的均聚物和共聚物的Langmuir单层
4. POLY(2-BUTYNE-1,4-DIYL)S AS PRECURSORS TO NOVEL SUBSTITUTED POLY ACETYLENES [C] . Symposium on electrical, optical, and magnetic properties of organic solid-state materials . 1998

机译：聚（2-丁酰基-1,4-二基）作为新型取代聚乙炔的前体
5. Application of routes to silicon-carbon bond formation for production of precursors to advanced materials: Part I: Investigation of cyclic and linear carbosilanes as single-source CVD precursors to silicon carbide. Part II: Synthesis and characterization of novel fluoro and cyano substituted poly(silylenemethylenes). [D] . Lienhard, Michael Alexander. 2000

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6. Fed-Batch Synthesis of Poly(3-Hydroxybutyrate) and Poly(3-Hydroxybutyrate-co-4-Hydroxybutyrate) from Sucrose and 4-Hydroxybutyrate Precursors by Burkholderia sacchari Strain DSM 17165 [O] . Miguel Miranda de Sousa Dias, Martin Koller, Dario Puppi, 2017

机译：蔗糖和4-羟基丁酸酯前体通过蔗糖伯克霍尔德菌菌株DSM 17165补料分批合成聚（3-羟基丁酸）和聚（3-羟基丁酸-co-4-羟基丁酸）
7. Langmuir-Blodgett mono- and multilayers of (di)alkoxy-substituted poly(p-phenylenevinylene) precursor polymers. 1. Langmuir monolayers of homo- and copolymers of (di)alkoxy-substituted precursor PPVs [O] . Hagting J.G., Vos R.E.T.P. de, Sinkovics K., 1999

机译：（二）烷氧基取代的聚（对亚苯基亚乙烯基）前体聚合物的Langmuir-Blodgett单和多层。 1.（二）烷氧基取代的前体PPV的均聚物和共聚物的Langmuir单层
8. Thermoset Polymers Made by Blending Poly (Carborane-Siloxane/ Silane-Acetylene)and Poly (Siloxane/Silane-Acetylene) [R] . Keller, T. M., Son, D. Y. 1996

机译：通过混合聚（碳硼烷 - 硅氧烷/硅烷 - 乙炔）和聚（硅氧烷/硅烷 - 乙炔）制成的热固性聚合物

POLY(2-BUTYNE-1,4-DIYL)S AS PRECURSORS TO NOVEL SUBSTITUTED POLY ACETYLENES

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