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Electrical Properties of Nanostructured Titanium Dioxide Thin Films Prepared By Sol-Gel Spin-Coating Method

机译:溶胶-凝胶旋涂法制备纳米结构二氧化钛薄膜的电学性能

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This paper investigated the electrical properties of nanostructured Titanium Dioxide (TiO_2) thin films prepared by the sol-gel method at different annealing temperatures. The precursor used was Titanium (IV) butoxide at concentration of 0.4 M. The TiO_2 thin films were deposited on the glass and silicon substrates by using the spin coating technique. The influence of annealing temperatures on the electrical, structural, surface morphology and optical properties of the films were characterized by I-V measurement, X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and UV-Vis Spectroscopy, respectively. It was found that the electrical properties of TiO_2 thin films were changed due to the changes of annealing temperatures. As the annealing temperatures rises, the resistivity of the film found to be decreased. The result also shows that films which does not applied annealing temperature called as deposited were found to be amorphous while the films with annealing temperature T = 350℃ and above became crystalline structure. The anatase phase can be obtained at annealing temperatures from T= 350℃ up to T= 500℃.
机译:本文研究了通过溶胶-凝胶法在不同退火温度下制备的纳米结构二氧化钛(TiO_2)薄膜的电学性能。所用的前体是浓度为0.4 M的丁醇钛(IV)。通过旋涂技术将TiO_2薄膜沉积在玻璃和硅基板上。分别通过I-V测量,X射线衍射(XRD),扫描电子显微镜(SEM)和UV-Vis光谱表征了退火温度对薄膜电学,结构,表面形态和光学性能的影响。发现随着退火温度的变化,TiO_2薄膜的电学性能发生了变化。随着退火温度的升高,发现膜的电阻率降低。结果还表明,未施加称为沉积的退火温度的膜是非晶态的,而退火温度T = 350℃以上的膜变成晶体结构。锐钛矿相可以在T = 350℃到T = 500℃的退火温度下获得。

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