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EIS INVESTIGATIONS OF ALKYD AND EPOXY COATINGS AS THEYARE CHEMICALLY STRIPPED FROM STEEL PANELS

机译:从钢板上化学剥离的醇酸和环氧树脂涂料的EIS研究

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Electrochemical Impedance Spectroscopy (EIS) has been employed to monitor, and model, realtimernchemical stripping and de-adhesion of select coatings from steel panels. Instead of therncustomary salt solution, a water based chemical stripper was used in a custom-built EIS cell. Inrneffect, the stripper was simultaneously used as the electrolyte for the EIS test as well as thernmodus operandi for stripping the coated panels.rnAlkyd (3 coats) and epoxy polyamide coatings (2 coats) were compared and contrasted during thernchemical stripping process. To examine the influence of pigment types in the coatings, a leafingrnaluminum alkyd finish in a 3 coat system was compared with an alkyd finish that containedrntitanium dioxide. The epoxy polyamide coating systems examined contained either non-leafingrnaluminum or titanium dioxide pigments.rnThe EIS data is discussed in terms of such multivariate factors as the pigment used in therndifferent coating types, the influence of coating chemistry and the unique chemistry of the waterrnbased chemical stripper.
机译:电化学阻抗谱(EIS)已被用于监视和建模,实时化学剥离和从钢板中选择的涂层脱粘。代替常规的盐溶液,在定制的EIS池中使用了水基化学汽提塔。效果是,该剥离剂同时用作EIS测试的电解质以及用于剥离涂层面板的热模操作。在化学剥离过程中比较和对比了醇酸树脂(3层)和环氧聚酰胺涂料(2层)。为了检查颜料类型对涂料的影响,将3涂层体系中的落叶铝醇酸面漆与含有二氧化钛的醇酸面漆进行了比较。所检查的环氧聚酰胺涂料体系包含非浸出性铝或二氧化钛颜料。讨论EIS数据时应考虑多种因素,例如不同涂料类型中使用的颜料,涂料化学的影响以及水基化学汽提塔的独特化学。

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