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Preparation of Nanoporous Super Thermal Insulation Material Compounded with Xonotlite-SiO_2-Aerogel and Characterization of the Pore Structure

机译:硬硅钙石-SiO_2-气凝胶复合纳米多孔超绝热材料的制备及孔结构表征

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摘要

Ultra-light calcium silicate material constructed with fibrous xonotlite crystals has an advantage of low-thermal conduction coefficient. But the microporous structure can hardly make a better performance in terms of super thermal insulation. Although nanoporous structure of SiO_2-aerogel satisfies the requirement, its tenacity is not strong enough to produce by itself blocky super thermal insulation material. This research, thus proposes to apply SiO_2-aerogel as nanoporous carrier in the process of preparation, with Ultra-light calcium silicate material constructed with fibrous xonotlite crystals as the matrix so as to prepare nanoporous super thermal insulation material compounded with Xonotlite-SiO_2-aerogeI via so-gel method and ethanol supercritical drying. SEM and pore size distribution techniques were here applied to characterize the morphology and pore structure of the composite material. The results show that the SiO_2-aerogels were better distributed in pore of calcium silicate matrix, with the pore size distribution of composite ranging from 10 nanometers to 50 nanometers, and average pore size less then 20 nm.
机译:由纤维硬硅钙石晶体构成的超轻硅酸钙材料具有低导热系数的优点。但是,在超绝热方面,微孔结构几乎不能获得更好的性能。尽管SiO_2-气凝胶的纳米孔结构可以满足要求,但其强度不足以单独生产块状超绝热材料。因此,本研究提出在制备过程中以SiO_2-气凝胶为纳米多孔载体,以纤维硬硅钙石晶体为基体构建的超轻硅酸钙材料,以制备与Xonotlite-SiO_2-aerogeI复合的纳米多孔超绝热材料。通过凝胶法和乙醇超临界干燥。扫描电镜和孔径分布技术在这里用于表征复合材料的形态和孔结构。结果表明,SiO_2-气凝胶在硅酸钙基体的孔中分布较好,复合材料的孔径分布在10纳米至50纳米之间,平均孔径小于20nm。

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