首页> 外文会议>Biennial Worldwide Conference on Refractories; 20031019-22; Osaka(JP) >Gibbs Free Energy Change of Solid State Reaction Determined by the Electrical Conductivity of the Oxide Product
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Gibbs Free Energy Change of Solid State Reaction Determined by the Electrical Conductivity of the Oxide Product

机译:固态反应的吉布斯自由能变化由氧化物产物的电导率决定

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摘要

The Gibbs energy change of solid state reaction of CaAl_4O_7 + 4Al_2O_3 = CaAl_(12)O_(19) was determined by electrical conductivity measurements. This technique is very useful to apply the reaction between the oxides of main group metal elements because the reaction does not exhibit any oxygen absorption or evolution, and a gas equilibration method can not be applied to such reactions.
机译:通过电导率测量确定CaAl_4O_7 + 4Al_2O_3 = CaAl_(12)O_(19)的固态反应的吉布斯能量变化。该技术对于在主族金属元素的氧化物之间进行反应非常有用,因为该反应不表现出任何氧吸收或放出,并且气体平衡方法不能应用于这种反应。

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