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Thin Film Composite (TFC) Membrane in Membrane Gas Absorption System

机译:膜气体吸收系统中的薄膜复合(TFC)膜

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Flue gas is a gas is released to the atmosphere via a flue and quite often refers to the combustion exhaust gas produced at power plants. Its composition generally depends on what is being burned, but usually consist of mostly carbon dioxide (CO2) and water vapor as well as nitrogen (N2) and excess oxygen. Lately, the removal of CO2 from flue gases has received intense attention due to the properties of CO2. It is widely known that CO2 is a one of the major greenhouses gases. Membrane gas absorption (MGA) is one technology used to remove the CO2. The present research focuses on the separation of CO2 from N2 using a thin film composite (TFC) membrane based on glutaraldehyde in MGA system. The THC membrane with glutaraldehyde as the selective layer on the top of different microfiltration supports with varying properties based on polypropylene (PP) and polyvinylidene fluoride (PVDF) were prepared. The effects of crucial parameters that effected TFC membrane performance such as coating solution concentration, membrane support porosity and nature of materials were investigated. Deionized water was employed as the liquid absorbent. The TFC membrane in combination with deionized water as an absorbent liquid was found to be a suitable for bulk CO2 removal using MGA system.
机译:烟道气是通过烟道释放到大气中的气体,通常指发电厂产生的燃烧废气。其成分通常取决于燃烧的物质,但通常主要由二氧化碳(CO2)和水蒸气以及氮气(N2)和过量的氧气组成。近来,由于CO 2的性质,从烟道气中去除CO 2受到了广泛的关注。众所周知,CO2是主要的温室气体之一。膜气体吸收(MGA)是一种用于去除CO2的技术。本研究的重点是在MGA系统中使用基于戊二醛的薄膜复合(TFC)膜从N2中分离出CO2。在聚丙烯(PP)和聚偏二氟乙烯(PVDF)的基础上,制备了具有戊二醛作为选择性层的THC膜,该膜位于不同微滤载体顶部,具有不同的性能。研究了影响TFC膜性能的关键参数(如涂料溶液浓度,膜载体孔隙率和材料性质)的影响。用去离子水作为液体吸收剂。已发现将TFC膜与去离子水作为吸收剂液体相结合,适用于使用MGA系统去除大量的CO2。

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